Journal
AICHE JOURNAL
Volume 57, Issue 6, Pages 1585-1594Publisher
WILEY
DOI: 10.1002/aic.12365
Keywords
miniemulsion; SMX elements; continuous; in-line; in situ; polymerization
Categories
Ask authors/readers for more resources
The preparation and stabilization of miniemulsion systems using SMX static mixers (in line with a pump and reservoir tank) and in situ generated surfactants is presented. Neutralization of a water-soluble base with an oil-soluble long chain acid, generating a in situ surfactant at the interface, results in rapid stabilization and emulsification compared to preformed surfactant that must diffuse to, then adsorb on the droplets. As the flow rates (50-75 g/s) and number of mixing elements (7-21 SMX mixers) in series increase, the emulsification time reduces by similar to 30-folds (14 vs. 0.5 min). The reduction in the emulsification time required to produce a stable emulsion at 75 g/s and 21 mixing elements more than compensated for the higher pressure in the emulsification loop, consuming five times less energy than what would be consumed when working at 50 g/s and 7 SMX elements. Subsequently, with the rapid emulsification step, it was possible to test the feasibility of a continuous process for direct emulsification followed by polymerization. Comparing this process with a batch process, similar results for the number of particles/number of droplets ratio and conversion were obtained, but the continuous process was accomplished in a single step. (C) 2010 American Institute of Chemical Engineers AIChE J, 57: 1585-1594, 2011
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available