Journal
PHYSICAL REVIEW A
Volume 80, Issue 4, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevA.80.042505
Keywords
configuration interactions; Dirac-Fock calculations; electron correlations; excited states; gold; isoelectronic series; oscillator strengths; silver; wave functions
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Funding
- Pedagogical University of Cracow Research
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Relativistic oscillator strengths are computed for ns(1/2)-np(1/2,3/2) transitions in silver and gold isoelectronic sequences employing configuration-interaction method with numerical Dirac-Fock wave functions generated with noninteger outermost core shell occupation number. This method is optimized to represent efficiently the core-valence electron correlation that is known to be important for transitions under consideration. The presented results are compared with our earlier data computed with core-valence correlation represented in the semiclassical core polarization picture within single configuration Dirac-Fock scheme as well as available experimental values.
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