Extended Roof snap-off for a continuous nonwetting fluid and an example case for supercritical CO2

A dominant mechanism for residual trapping of a nonwetting fluid in porous media during imbibition is snap-off or the disconnection of a continuous stream of the nonwetting fluid when it passes through pore constrictions and when a criterion based on capillary pressure imbalance is met. While quasi-static criteria for Roof snap-off have been defined for pores based on the imbalance between capillary pressure across the front/tail meniscus and local capillary pressure at the pore throat, and expressed in terms of pore body to pore throat ratio for simplification, we extended the previous quasi-static snap-off criterion by considering the local capillary pressure imbalance between the pore body and the pore throat for both circular and noncircular pores when the wetting film exists. We then used the criterion to analyze results from computational fluid dynamics (CFD) simulations of multi-phase flow with supercritical CO2 as the nonwetting fluid and water as the wetting fluid. The extended criterion successfully described most situations we modeled. Furthermore, we compared fluid interface shape for a noncircular 3D pore predicted by the minimum surface energy (MSE) theory against 3D CFD simulations. While the fluid interface shape at the pore throat for 3D simulation was consistent with the shape predicted by MSE theory, the shape could not be successfully predicted by the MSE theory at the upstream and downstream pore body. Moreover, film flow existed for the noncircular pore at the downstream pore body. Published by Elsevier Ltd.