Journal
ADVANCES IN SPACE RESEARCH
Volume 51, Issue 12, Pages 2235-2240Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.asr.2013.01.029
Keywords
Hydantoin; 5-Substituted hydantoins; UV radiation; Prebiotic photochemistry; Photolysis products
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Aqueous solutions of 5-substituted hydantoins were irradiated with ultraviolet (UV) light, to investigate their structural stability against UV radiation as well as the possible photolysis products. The photolysis products were identified and the degree of photolysis was measured using reversed-phase and ion-exchange high-performance liquid chromatography. Hydantoin (2,4-imidazolidinedione) was dominantly detected as a photolysis product of 5-substituted hydantoins. With hydrolysis of UV-irradiated 5-substituted hydantoins, glycine and alanine were dominantly detected. These experimental results are important for the prebiotic photochemistry of 5-substituted hydantoins in the formation of hydantoin since they have been detected in Solar System materials. (C) 2013 COSPAR. Published by Elsevier Ltd. All rights reserved.
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