Zircon U-Pb ages, geochemistry, and Sr-Nd-Pb isotopic compositions of Middle Triassic granodiorites from the Kaimuqi area, East Kunlun, Northwest China: implications for slab breakoff

The Qimantage area of Northwest China lies in the western part of the East Kunlun Orogenic Belt, and is dominated by late Permian to Late Triassic granitoids. Among these, the Middle Triassic granitoids are mainly distributed south of the North Kunlun Fault, and consist of two main granitic assemblages: the Kaimuqi assemblage in the east and the Mositu assemblage in the west. To better constrain the Indosinian tectonic evolution of this area, we present data on the geochronology, geochemistry, and petrology of ore-bearing granodiorites from the Kaimuqi area in eastern Qimantage. The granodiorite samples have porphyritic or fine-grained textures. Laser ablation inductively coupled plasma mass spectrometry U-Pb zircon dating yields emplacement ages of 238-242Ma, interpreted here as the result of the Middle Triassic magmatism. The granodiorites are mostly of the high-K calc-alkaline series, and are enriched in light rare earth elements, depleted in heavy rare earth elements such as Nb, Ta, P, and Ti, and have weak negative Eu (Eu/Eu*) anomalies. The Kaimuqi granodiorites have lower SiO2 and Sr contents, and higher Na2O/K2O ratios than the Mositu granodiorites. They also show initial Sr-87/Sr-86 ratios of 0.712151-0.715436, epsilon Nd(t) values of -7.4 to -6.3, and two-stage Nd model ages of 1.53-1.61Ga. Together with their radiogenic Pb isotopic ratios for Pb-206/Pb-204((t)) (18.271-18.622), Pb-207/Pb-204((t)) (15.637-15.651), and Pb-208/Pb-204((t)) (38.452-37.870), these data indicate both mantle and crustal contributions to the source of the granodiorites. Field investigations show that Middle Triassic granitoids in both the Mositu and Kaimuqi assemblages contain large numbers of mafic microgranular enclaves, which supports an interpretation of mantle and crustal magmatic mixing. Based on a comparison of these results with data from coeval granites in the Mositu assemblage, we propose that the Middle Triassic granitoids in the Qimantage area were produced at ca. 240Ma, as a result of the end of subduction and the initiation of collision during the Variscan-Indosinian orogeny. Magma mixing may be interpreted as the result of slab breakoff in a subduction zone environment, which led to fluid metasomatism and induced partial melting of an enriched lithospheric mantle, resulting in the formation of voluminous granitic magma.