Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 360, Issue 23, Pages 4480-4484Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201801141
Keywords
C,C-palladacycles; C-H activation; Alkylation; Palladium; Benzofulvenes
Categories
Funding
- National Natural Science Foundation of China [216721626, 2137217]
- Shanghai Science and Technology Commission [14DZ2261100]
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An approach for the synthesis of benzofulvenes has been developed through palladium-catalyzed sequential three-component reactions. The reactions likely involve C,C-palladacycles as the key intermediates. The palladacycles are generated through cascade reactions of aryl halides and alkynes, and then reacted with CH2Br2 to form benzofulvenes as the final products.
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