Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 360, Issue 12, Pages 2364-2369Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201800140
Keywords
carbon dioxide; catalysis; reduction; methylation; formylation
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Funding
- National Natural Science Foundation of China [21772208, 21702212, 21602230, 21633013]
- Natural Science Foundation of Jiangsu Province [BK20161260, BK20170404]
- Hundred-Talented Program of the Chinese Academy of Sciences
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We describe herein an efficient organocatalytic system for the selective N-methylation and N-formylation of amines with carbon dioxide (CO2) as a sustainable Cl feedstock and polymethylhydrosiloxane (PMHS) as a cost-effectvie reducing reagent. High-yielding N-methylation products are obtained with low catalyst loading (1%) of DBU. Selective N-formylation of amines is achieved using the same catalytic system at a lower reaction temperature.
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