Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 360, Issue 18, Pages 3488-3491Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201800630
Keywords
dialkyl(heteroaryl)phosphine sulfides; tetraalkyldiphosphine disulfides; phosphinylation; desulfurization; Rh catalysis
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Funding
- AMED [JP18am0101100]
- JSPS KAKENHI [17 K19112, 15H00911]
- Tohoku University Center for Gender Equality Promotion (TUMUG)
- Morinomiyako Project for Empowering Women in Research
- Grants-in-Aid for Scientific Research [15H00911] Funding Source: KAKEN
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Dialkyl(heteroaryl) phosphine sulfides were synthesized by the rhodium-catalyzed exchange reaction of heteroaryl aryl sulfides and tetraalkyldiphosphine disulfides. The reaction has a broad applicability, giving diverse dialkyl(heteroaryl) phosphine sulfides containing five-and six-membered heteroaryl groups. Various dialkyl(heteroaryl) phosphines were obtained by desulfurization.
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