4.7 Article

Rhodium-Catalyzed Synthesis of Dialkyl(Heteroaryl)Phosphine Sulfides by Phosphinylation of Heteroaryl Sulfides

Journal

ADVANCED SYNTHESIS & CATALYSIS
Volume 360, Issue 18, Pages 3488-3491

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201800630

Keywords

dialkyl(heteroaryl)phosphine sulfides; tetraalkyldiphosphine disulfides; phosphinylation; desulfurization; Rh catalysis

Funding

  1. AMED [JP18am0101100]
  2. JSPS KAKENHI [17 K19112, 15H00911]
  3. Tohoku University Center for Gender Equality Promotion (TUMUG)
  4. Morinomiyako Project for Empowering Women in Research
  5. Grants-in-Aid for Scientific Research [15H00911] Funding Source: KAKEN

Ask authors/readers for more resources

Dialkyl(heteroaryl) phosphine sulfides were synthesized by the rhodium-catalyzed exchange reaction of heteroaryl aryl sulfides and tetraalkyldiphosphine disulfides. The reaction has a broad applicability, giving diverse dialkyl(heteroaryl) phosphine sulfides containing five-and six-membered heteroaryl groups. Various dialkyl(heteroaryl) phosphines were obtained by desulfurization.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available