Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 360, Issue 21, Pages 4049-4053Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201800844
Keywords
Benzimidate; Isoquinoline; Oxidant-free; Ruthenium catalyst; Sulfoxonium ylide
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Funding
- Natural Science Foundation of China [21372056]
- PCSIRT [IRT 1231]
- Natural Science Foundation of Zhejiang Province [LY17B020007]
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A ruthenium-catalyzed direct mono-C-H functionalization/annulation cascade reaction of benzimidates and sulfoxonium ylides has been developed. The reaction proceeds smoothly with a broad range of substrates, giving access to a variety of isoquinoline derivatives in moderate to good yields using an organic acid additive under oxidant free conditions.
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