Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 360, Issue 20, Pages 3894-3899Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201800740
Keywords
Photocatalysis; C-F bond cleavage; Trifluoromethylation; Iridium; Sodium triflinate
Categories
Funding
- Nanjing Tech University [39837118, 39837101]
- Singapore Ministry of Education Academic Research Fund [Tier 1 grant] [RG5/15, RG111/16]
- SICAM Fellowship from Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanyang Technological University
Ask authors/readers for more resources
A convenient photoredox-catalyzed defluorinative trifluoromethylation of alpha-trifluoromethyl alkenes and gem-difluoroalkenes is developed. The reactions proceeded efficiently via trifluoromethyl radical addition followed by beta-fluorine elimination process, providing a new entry to multifluorinated alkenes in moderate to good yields with excellent stereoselectivity.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
