Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 360, Issue 20, Pages 3884-3888Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201800661
Keywords
isomerization; aerobic oxidative iodination; alpha-iodoketones; alpha-aminoketones; allylic alcohol
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Funding
- Swedish Research Council through Formas
- Knut and Alice Wallenberg Foundation
- Slovenian Research Agency [P1-0134, MR36492, ARRS-SP-2990/17]
- Generalitat Valenciana
- European Social Fund
- Universitat de Valencia (Spain)
- COST Action CARISMA (Catalytic Routines for Small Molecule Activation) [CM1205]
- Ad-Futura grant
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An efficient method for the synthesis of alpha-iodoketones from allylic alcohols and elemental iodine is reported. We show in this paper that the isomerization of allylic alcohols catalyzed by iridium(III) complexes can be combined with an aerobic oxidative iodination protocol, resulting in a straightforward method for the synthesis of a wide range of alpha-iodoketones as single constitutional isomers and in high yields under mild reaction conditions.
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