Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 361, Issue 4, Pages 630-653Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201800709
Keywords
cyclization; heterocycles; Michael addition; beta-nitroacrylates; nitroolefins
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Funding
- University of Camerino
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beta-Nitroacrylates are an important subclass of nitroolefins in which an ester and a nitro group are simultaneously linked, in alpha- and beta-positions, to a double bond. This peculiarity makes these nitro derivatives highly reactive with a plethora of nucleophiles, very often under extremely mild reaction conditions, and thus they can serve as excellent building blocks towards highly functionalized materials. Based on the growing application of beta-nitroacrylates in organic synthesis, we considered it to be useful to highlight in this review the most important results obtained over the last ten years.
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