Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 360, Issue 19, Pages 3667-3671Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201800826
Keywords
Transition metal-free; cross-coupling; alkenylboronic acids; sp(3)-carbon electrophiles
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Funding
- National Science Foundation of China [NSFC-21472018, 21672035]
- National Science Foundation [CHE-1401700]
- China Scholarship Council
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Diverse alkenylboronic acids react smoothly with various sp(3)-carbon electrophiles such as unactivated alkyl triflates in the presence of mild bases such as K3PO4. The reaction protocol is very mild and thereby enables high functional group tolerance. This transition metal-free condition is orthogonal towards the classic transition metal catalyzed Suzuki coupling.
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