Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 356, Issue 14-15, Pages 2895-2906Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201400370
Keywords
alkenes; Langlois' reagent; radical reactions; sodium trifluoromethanesulfinate (CF3SO2Na); trifluoromethylation
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Funding
- Chongqing Vocational Institute of Safety Technology
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The incorporation of a trifluoromethyl (CF3) group into organic compounds is of great importance in pharmaceutical, agricultural, and materials science. Trifluoromethylation based on radical intermediates, as a valuable alternative transformation using the inexpensive and stable solid sodium trifluoromethanesulfinate (CF3SO2Na; Langlois' reagent), has attracted much attention and has become a hot research field. This review examines recent advances in radical trifluoromethylation reactions with CF3SO2Na as CF3 source.
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