Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 356, Issue 13, Pages 2763-2768Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201400677
Keywords
asymmetric photoreactions; hydrogen bonding photocatalysis; organophotocatalysis; photochirogenesis; thiourea photocatalysis
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Funding
- NDSU
- NSF [CHE-1213880, CHE-1111392]
- Arthur C. Cope Scholar Award
- NDSU graduate school
- UGC, India
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1111392] Funding Source: National Science Foundation
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1213880] Funding Source: National Science Foundation
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The efficiency of [2+2] photocycloadditions of 4-alkenylcoumarins was evaluated with various thiourea skeletons to develop thiourea-based catalysts for promoting photochemical reactions. Our results indicate that the excited state chemistry is dependent on the nature of the thiourea catalyst employed to activate the photoactive substrate.
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