Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 356, Issue 13, Pages 2794-2800Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201400580
Keywords
alkenes; cross-coupling; dual catalysis; gold; photocatalysis
Categories
Funding
- European Research Council under the European Community [25936]
- NRW Graduate School of Chemistry
- Alexander von Humboldt Foundation
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Intermolecular three-component oxyarylation reactions of simple alkenes have been developed using a dual gold and photoredox catalytic system. Inexpensive organic dyes could be employed as the photocatalyst using aryldiazonium salts, while the combination of gold and iridium catalysts allowed for diaryliodonium compounds to be employed as the source of the arene coupling partner. In both cases, alpha-arylated ether products were generated under remarkably mild conditions using readily accessible visible light sources.
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