Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 356, Issue 11-12, Pages 2485-2492Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201400291
Keywords
all-carbon quaternary stereocenters; carbocycles; co-catalysis; dynamic transformations; heterogeneous synergistic catalysis
Categories
Funding
- European Union
- Mid Sweden University
- Swedish National Research Council
- VR
- Swedish Governmental Agency for Innovation Systems (VINNOVA)
Ask authors/readers for more resources
A modular design for a novel heterogeneous synergistic catalytic system, which simultaneously activates the electrophile and nucleophile by the combined activation modes of a separate metal and non-metal catalyst, for asymmetric cascade transformations on a solid surface is disclosed. This modular catalysis strategy generates carbocycles (up to 97.5: 2.5 er) as well as spirocyclic oxindoles (97.5: 2.5 to > 99: 0.5 er), containing all-carbon quaternary centers, in a highly enantioselective fashion via a one-pot dynamic relay process.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available