Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 356, Issue 17, Pages 3525-3529Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201400845
Keywords
1,2-addition; cyclometallated palladium complexes; formaldehyde; N-heterocyclic carbenes; palladium catalyst
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Cyclometallated NHC palladium complexes prepared from palladium(II) acetate [Pd(OAc)(2)] and unsymmetrical 1,3-diarylimidazolinium salts catalyzed the hydroxymethylation of (hetero)arylboronic acids using an excess amount of formalin to afford (hetero)arylmethanols in good to satisfactory yields.
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