Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 356, Issue 2-3, Pages 383-387Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201300830
Keywords
2; 3-dihydrobenzofurans; ortho-quinone methides; synthesis
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Funding
- National Natural Science Foundation of China [21125208, 20921092]
- National Basic Research Program of China [2010CB833300]
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A facile method for the stereoselective synthesis of trans-2,3-dihydrobenzofurans from ortho-quinone methides in situ generated from readily available 2-alkyl-substituted phenols using silver oxide-mediated oxidation has been developed. Additionally, the 2,3-dihydrobenzofurans can be further transformed into the aromatized 2,3-disubstituted benzofurans in the presence of DDQ.
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