Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 356, Issue 14-15, Pages 2913-2918Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201400242
Keywords
alkenes; isoxazoles; oxyfluorination; Selectfluor; silver
Categories
Funding
- Natural Science Foundation of China [21172060]
- Specialized Research Fund for the Doctoral Program of Higher Education [20120161110041]
- Hunan Provincial Natural Science Foundation of China [13JJ2018]
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A new silver-catalyzed oxyfluorination of unactivated alkenes using commercially available Selectfluor as the fluorine source is presented. This method provides a new access to 5-(fluoromethyl)4,5-dihydroisoxazoles, and represents a new example of alkene 1,2-difunctionalization by simultaneously forming two new carbon-heteroatom bonds.
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