Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 356, Issue 5, Pages 1085-1092Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201300811
Keywords
C-2 alkenylation; CH activation; indoles; oxygen oxidation; palladium-catalyzed reaction
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Funding
- National Natural Science Foundation of China [NSFC-20972126, 21272185]
- Program for New Century Excellent Talents in University of the Ministry of Education, China [NCET-10-0937]
- Education Department of Shaanxi Provincial Government [09JK776]
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A general and efficient palladium-catalyzed intermolecular direct C-2 alkenylation of indoles using oxygen as the oxidant has been developed. The reaction is of complete regio- and stereoselectivity. All products are E-isomers at the C-2-position with no Z-isomers and 3-substituted products were detected.
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