Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 356, Issue 8, Pages 1753-1760Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201301114
Keywords
asymmetric catalysis; domino reactions; functionalized chromanes; functionalized tetrahydroxanthenones; organocatalysis
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Funding
- NSFC [21202149]
- Zhejiang Natural Science Foundation [Y4110348]
- Foundation of Zhejiang Education Committee [Y201225109]
- Foundation of Zhejiang Key Course of Chemical Engineering and Technology
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The efficient simultaneous activation of cyclohexenones or simple alkyl acyclic enones and 2-hydroxynitrostyrenes was realized by using a prolinol thioether catalyst. Thus, a highly chemo-, diastereo- and enantioselective synthesis of functionalized tetrahydroxanthenones and chromanes with up to three contiguous stereocenters was developed.
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