Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 355, Issue 18, Pages 3527-3531Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201300765
Keywords
asymmetric catalysis; borylation; copper; silanes; synthetic methods
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Funding
- Japan Society for the Promotion of Science (JSPS) [G002]
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An asymmetric monoborylation of alkenylsilanes catalyzed by a copper(I) complex with the chiral bisphosphine ligand BenzP* is reported. The reaction proceeded with excellent regioselectivity and high enantioselectivity to afford the corresponding optically active organoboronate esters with a stereogenic CB bond containing a vicinal silyl group. The synthetic utility of the product is demonstrated through stepwise transformations to multifunctional optically active compounds in a stereospecific manner.
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