Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 355, Issue 4, Pages 673-678Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201201085
Keywords
carboxylic acids; cross-coupling decarboxylation; electron-transfer mediators; enamides; re-oxidation
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- MOH
- UGC
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The purple-coloured iron peroxo complex [Fe(III)EDTA(2-O2)]3 as a novel reagent system for Pd-catalyzed decarboxylative ortho-acylation of acetanilides with -oxocarboxylic acids at room temperature in aqueous media has been realized. This reaction provides an effective access to ortho-acylacetanilides under mild conditions.
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