Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 355, Issue 11-12, Pages 2158-2164Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201300311
Keywords
alkylation; CH activation; cross-coupling reactions; visible light catalysis
Categories
Funding
- Ministry of Science and Technology of China [2009CB220008, 2013CB834505, 2013CB834804]
- National Natural Science Foundation of China [21090343, 91027041]
- Knowledge Innovation Program of the Chinese Academy of Sciences
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By combining the visible-light catalyst, Ru(bpy)(3)Cl-2, and transition metal salts, Cu(OTf)(2), we are able to functionalize secondary amines to form Csp3Csp3 bonds with -keto esters efficiently by an aerobic oxidative coupling reaction under visible light irradiation at ambient conditions.
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