Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 355, Issue 11-12, Pages 2222-2226Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201300468
Keywords
acylarylation; decarboxylation; oxindoles; radicals; silver catalysts
Categories
Funding
- National Natural Science Foundation of China [21102110, 21102111]
- Doctoral Fund of the Ministry of Education of China [20110201120076]
- Fundamental Research Funds of the Central Universities
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A mild and efficient silver-catalyzed acylarylation of activated alkenes with easily available alpha-oxocarboxylic acids has been developed. The reactions provide a rapid access to a variety of functionalized oxindoles via a tandem decarboxylative radical cyclization strategy. This transformation proceeds well under mild reaction conditions and exhibits excellent functional group tolerance, affording the desired oxindoles in good to excellent yields.
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