Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 355, Issue 11-12, Pages 2203-2207Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201300199
Keywords
CH activation; electron transfer; organocatalysis; photochemistry; radical reactions
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Funding
- Japan Society for the Promotion of Science (JSPS) [24790015]
- Grants-in-Aid for Scientific Research [24790015] Funding Source: KAKEN
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We report the visible-light-induced trifluoromethylation of arenes and heteroarenes using sodium trifluoromethanesulfinate catalyzed by anthraquinone-2-carboxylic acid. This reaction is a metal-free trifluoromethylation of arenes and heteroarenes catalyzed by a photoredox organocatalyst. Perfluoroalkylated arenes were also produced using sodium perfluoroalkylsulfinates.
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