Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 355, Issue 14-15, Pages 2745-2755Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201300375
Keywords
addition reactions; asymmetric catalysis; carboxylic acids; CC bond formation; decarboxylation
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Funding
- QingDao Agricultural University [631303]
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This review examines recent advances in asymmetric catalytic decarboxylative addition reactions which have become a powerful method to form CC and CX bond using relatively cheap and stable carboxylic compounds. In these reactions, new CC or CX bonds are formed with extrusion of carbon dioxide (CO2). Asymmetric decarboxylative addition reactions have become alternatives to traditional addition reactions. Various asymmetric reactions between carboxylic acids and unsaturated compounds are summarized. The challenges and opportunities of these reactions are discussed.
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