Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 355, Issue 9, Pages 1724-1728Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201300174
Keywords
CH activation; olefination; oxidation; rhodium; Weinreb amides
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Funding
- Chinese Academy of Sciences
- Ministry of Education [SRFDP 20123402110040]
- National Science Foundation of China [21102138]
- University of Science and Technology of China (USTC)
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A rhodium(III)-catalyzed oxidative CH olefination directed by Weinreb amides, a class of well developed versatile building blocks in organic synthesis, has been developed with air as the terminal oxidant. The reactions proceed with excellent reactivity, good functional group tolerance and high yields.
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