Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 355, Issue 11-12, Pages 2430-2440Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201300439
Keywords
CC bond formation; hafnocenes; homogeneous catalysis; Lewis acids; perfluorobutane(benzene)sulfonates
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Funding
- NSFC [21172061, 21273068, 21273067, 21003040]
- NSF of Hunan Province [10JJ1003, 11JJ5009]
- Fundamental Research Funds for the Central Universities
- JSPS
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The two air-stable (2)-hydroxy-bridged binuclear hafnocene perfluorobutanesulfonate and perfluorobenzenesulfonate complexes were successfully synthesized. The high catalytic activity and recyclability of these complexes were exemplified for various carbon-carbon bond formation reactions. Compared with our previously reported hafnocene perfluorooctanesulfonate, these complexes show stronger Lewis acidity and better catalytic activity, and should find broad applications in organic synthesis.
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