Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 355, Issue 7, Pages 1284-1290Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201300026
Keywords
copper; dehalogenation; dehydrogenation; oxygen; pyridazinones
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Funding
- Beijing Natural Science Foundation [7112088]
- National Basic Research Program of China [2012CB518000]
- National Natural Science Foundation of China [21202003/21172012]
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A copper-catalyzed cascade dehydrogenative and dehalogenative reaction of halogenated 6-phenyl-4,5-dihydropyridazin-3(2H)-ones to 6-phenylpyridazin-3(2H)-ones has been developed. Moreover, the catalytic system consisting of copper(II) acetate/sodium carbonate/pyridine exhibits high reactivity and selectivity with oxygen as the terminal oxidant.
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