Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 355, Issue 7, Pages 1291-1296Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201300126
Keywords
migration of the sulfonyl group; N-propargylic sulfonohydrazone; [3; 3] rearrangements; (1E; 3E)-2-sulfonyl-1; 3-dienes
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Funding
- National Natural Science Foundation of China [21072159, 21272190]
- PCSIRT in University
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A new method for the stereoselective synthesis of highly substituted (1E,3E)-2-sulfonyl-1,3-dienes from N-propargylic sulfonohydrazone derivatives has been developed via copper(I)-catalyzed [3,3]rearrangement and highly regioselective migration of the sulfonyl group.
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