4.7 Article

Tetraethylammonium Bromide-Catalyzed Oxidative Thioesterification of Aldehydes and Alcohols

Journal

ADVANCED SYNTHESIS & CATALYSIS
Volume 355, Issue 18, Pages 3558-3562

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201300584

Keywords

metal-free conditions; oxidative coupling; tetraalkylammonium bromides; thioesterification

Funding

  1. National Natural Science Foundation of China [21172106, 21074054]
  2. National Basic Research Program of China [2010CB923303]
  3. Research Fund for the Doctoral Program of Higher Education of China [20120091110010]

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A metal-free, tetraethylammonium bromide-catalyzed oxidative coupling of aldehydes or alcohols with thiophenols or disulfides has been developed. This protocol affords an efficient and inexpensive approach to the synthesis of a wide range of thioesters in high yields.

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