Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 355, Issue 10, Pages 2071-2075Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201300258
Keywords
aldehydes; hydroformylation; phosphane ligands; regioselectivity; rhodium; self-assembly; surfactants; sustainable chemistry; water chemistry
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Funding
- DFG, the International Research Training Group Catalysts and Catalytic Reactions for Organic Synthesis [IRTG 1038]
- Krupp Foundation
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We herein demonstrate a hydroformylation at room temperature and ambient pressure (RTAP) using our Rh/6-DPPon (1) system in aqueous media. The hydrogen bonding network of the ligand backbone stays intact, exemplified by the excellent regioselectivity for the linear aldehyde. Various substrates with different functional groups (with some prone to hydrolysis) are stable under the applied conditions and can undergo hydroformylation resulting in good yields.
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