Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 354, Issue 9, Pages 1707-1711Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100630
Keywords
alkene oxidation; aqueous phase chemistry; heterogeneous catalysis; supported iron oxide nanoparticles
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Funding
- Payame Noor University
- Iran National Science Foundation (INSF)
- Ministerio de Ciencia e Innovacion, Gobierno de Espana through a Ramon y Cajal [RYC-2009-04199]
- MICINN [CTQ-2011-28954-C02-02]
- Consejeria de Ciencia e Innovacion, Junta de Andalucia contract [P10-FQM-6711]
- short stay fellowship under Incentivos para Actividades de caracter cientifico y tecnico at the EPA in Cincinnati [IAC-2010-2-4512]
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Iron oxide nanoparticles supported on mesoporous silica-type materials have been successfully utilized in the aqueous selective oxidation of alkenes under mild conditions using hydrogen peroxide as green oxidant. The supported catalyst could be easily recovered after completion of the reaction and reused several times without any loss in activity (no metal leaching observed during the reaction), constituting a facile and straightforward example of aqueous oxidation chemistry promoted by iron-based heterogeneous systems.
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