4.7 Article

Ruthenium Pincer-Catalyzed Cross-Dehydrogenative Coupling of Primary Alcohols with Secondary Alcohols under Neutral Conditions

Journal

ADVANCED SYNTHESIS & CATALYSIS
Volume 354, Issue 13, Pages 2403-2406

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201200438

Keywords

cross-esterification; dehydrogenation; homogeneous catalysis; oxidative coupling; ruthenium pincer complexes

Funding

  1. European Research Council under the FP7 framework (ERC) [246837]
  2. Israel Science Foundation
  3. Helen and Martin Kimmel Center for Molecular Design

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Cross-dehydrogenative coupling of primary alcohols with secondary alcohols to obtain mixed esters with the liberation of molecular hydrogen is achieved in high yield and good selectivity under neutral conditions, using a bipyridyl-based PNN ruthenium(II) pincer catalyst.

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