4.7 Article

Gold Nanoparticles Supported on the Periodic Mesoporous Organosilicas as Efficient and Reusable Catalyst for Room Temperature Aerobic Oxidation of Alcohols

Journal

ADVANCED SYNTHESIS & CATALYSIS
Volume 354, Issue 7, Pages 1319-1326

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100802

Keywords

aerobic oxidation; alcohols; gold nanoparticles; heterogeneous catalysts; periodic mesoporous organosilica (PMO)

Funding

  1. IASBS Research Council
  2. INSF Research Council

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Gold nanoparticles supported on the channels of a bifunctional periodic mesoporous organosilica, were found to be a highly efficient catalyst system for the aerobic oxidation of various types of alcohols into their corresponding aldehydes and ketones at room temperature. The catalyst showed no significant loss of efficiency for the aerobic oxidation of benzyl alcohol to give benzaldehyde after 7 reaction cycles.

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