Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 354, Issue 16, Pages 3122-3126Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201200133
Keywords
1,4-addition; asymmetric hydrophosphination; diarylphosphines; nitroalkenes; pincer palladium catalysts
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Funding
- NSFC [20902099, 21172238]
- National Basic Research Program of China (973 Program) [2010CB833300]
- SIOC
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A highly stereoselective asymmetric 1,4-addition of diarylphosphines to nitroalkenes catalyzed by a bis(phosphine) pincer-palladium complex has been developed for the synthesis of chiral P,N compounds with good to excellent enantioselectivities (up to 94% ee) under mild conditions.
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