Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 354, Issue 2-3, Pages 321-327Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100877
Keywords
chemoselectivity; molybdenum; nitro compounds; reduction; sulfoxides
Categories
Funding
- Ministerio de Ciencia e Innovacion (MICINN)
- FEDER [CTQ2010-15358, CTQ2009-09949/BQU]
- Junta de Castilla y Leon [BU021 A09, GR-172]
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Pinacol is disclosed as a new chemoselective and environmentally benign reducing agent for sulfoxides and nitroaromatics assisted by readily available dichlorodioxomolybdenum(VI) complexes as catalysts. A wide range of substrates including those bearing challenging functional groups has been efficiently and selectively reduced with acetone and water being the only by-products of these reactions.
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