Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 354, Issue 11-12, Pages 2157-2161Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201200510
Keywords
acrylic keto diesters; acylsilanes; photochemical induction; silylacylation; silylated chromones
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Funding
- Fonds der Chemischen Industrie
- Alexander von Humboldt Foundation
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Visible light initiates the stereoselective formation of two new bonds, a C-C and a C-Si bond, during the addition of acylsilanes to alkynes. At room temperature this photochemically induced transformation can be applied for the preparation of chromone derivatives in a highly atom-economic manner.
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