Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 354, Issue 2-3, Pages 497-504Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100672
Keywords
alcohols; dehydrogenation; homogeneous catalysis; ruthenium; transition metals
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Funding
- European Research Council (ERC) [246837]
- Israel Science Foundation
- MINERVA foundation
- Kimmel Center for Molecular Design
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The complex bis(acetonitrile)bis(triphenylphosphine)ruthenium(II) sulfate [Ru(PPh3)2(NCCH3)2(SO4)], fully characterized spectroscopically and by a single crystal X-ray study, catalyzes at 110 degrees C the direct transformation of primary alcohols to the corresponding acetals with liberation of molecular hydrogen. The formation of acetals proceeds via direct substitution of the hydroxy group of the hemiacetal intermediate by an alcohol molecule. The closely related bis(triphenylphosphine)ruthenium(II) acetate [Ru(PPh3)2(OAc)2] catalyzes the conversion of primary alcohols to the corresponding esters rather than acetals.
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