Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 354, Issue 4, Pages 563-568Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100739
Keywords
asymmetric organocatalysis; 1; 2-keto esters; Michael addition; pronucleophiles; Takemoto's catalyst
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Funding
- French Research Ministry
- Agence Nationale pour la Recherche [ANR-07-CP2D-06]
- Universite Paul Cezanne
- CNRS [ism2-UMR 7313]
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When activated with Takemotos catalyst, 1,2-keto esters constitute versatile nucleophiles in the Michael addition reaction with nitroalkenes affording synthetically valuable, optically active anti-adducts in very good yields and high enantiomeric excesses.
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