Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 354, Issue 4, Pages 579-583Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100711
Keywords
C?H activation; olefination; olefins; oxazolines; rhodium
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Funding
- Deutsche Forschungsgemeinschaft [SFB 858]
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The rhodium(III)-catalyzed oxidative olefination of 2-aryloxazolines is described and has been employed for the synthesis of olefin-oxazoline ligands (OlefOx). The highly modular synthesis starting from readily available 2-aryloxazolines can be performed under an atmosphere of air as the terminal oxidant with catalytic amounts of copper(II)-acetate.
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