4.7 Article

Facile Preparation and Reactivity of Magnetic Nanoparticle- Supported Hypervalent Iodine Reagent: A Convenient Recyclable Reagent for Oxidation

Journal

ADVANCED SYNTHESIS & CATALYSIS
Volume 354, Issue 2-3, Pages 313-320

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100601

Keywords

alcohols; aldehydes; hypervalent iodine compounds; oxidation; supported catalysts

Funding

  1. Nanjing University of Science and Technology
  2. Jiangsu Higher Education Institutions [CX2211 0266]

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A simple three-step preparation of magnetic nanoparticle-supported (diacetoxyiodo)benzene starting from 4-iodobenzoic acid is described. The nanoparticle reagent was obtained with good loading levels and has been successfully used for efficient oxidation of a wide range of alcohols. The supported reagent demonstrated comparable activity with that of its homogeneous counterpart (diacetoxyiodo)benzene and could be simply recycled with the assistance of an external magnet.

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