Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 354, Issue 10, Pages 1902-1908Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201200106
Keywords
C?H activation; cycloamidination; heteroaromatic compounds; isocyanides; palladium
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Funding
- National Science Foundation of China [21072190]
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An efficient method for the synthesis of nitrogen heterocycles containing a cyclic amidine moiety has been developed. The process involves palladium-catalyzed C(sp2)?H activation and isocyanide insertion starting with readily accessible ortho-heteroarene-substituted aniline derivatives under mild conditions.
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