Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 353, Issue 9, Pages 1463-1466Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100035
Keywords
ambient temperature process; catalysis; copper; 1,3-diynes; N,N,N ',N '-tetramethylethane-1,2-diamine
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Funding
- National Natural Science Foundation of China [21072143]
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A facile and efficient pathway for the copper iodide and ligand N,N,N',N'-tetramethylethane-1,2-diamine promoted homocoupling reaction of terminal alkynes under ambient temperature and air as an oxidant was reported. The alkynes, including aromatic alkynes and aliphatic alkynes, could afford the symmetrical 1,4-disubstituted 1,3-diynes in good to excellent yields.
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