Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 353, Issue 2-3, Pages 325-330Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201000689
Keywords
cascade reactions; C-H activation; fluorine; indoles; palladium
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Funding
- National Science Foundation of China [20772145]
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A novel palladium-catalyzed synthesis of substituted 3-methylene-3H-indoles from readily accessible alkynylimines has been developed. A wide variety of 2-fluoroalkyl-3-methylene-3H-indoles were synthesized in moderate to good yields through this cascade carbopalladation/C-H activation process. This reaction can also be expanded to non-fluorinated substrates.
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