Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 353, Issue 4, Pages 533-537Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201000878
Keywords
N-arylamination; C-N coupling; palladium
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A novel class of C-2-substituted oxaphosphole-based monophosphines 1-4 has been synthesized. Palladium complexes derived from these ligands and their C-2-unsubstituted analogs provide general catalysts for amination reactions of challenging aryl and heteroaryl halides with sterically hindered anilines and alkylamines.
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