Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 353, Issue 2-3, Pages 469-474Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201000768
Keywords
pi-activated alcohols; calcium catalysts; direct amination; room temperature alkylation of amines
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A calcium-catalyzed direct amination of pi-activated alcohols with different nitrogen nucleophiles under very mild reaction conditions is presented. The high reactivity of the calcium catalyst allows for an efficient conversion of secondary and tertiary benzylic and allylic as well as tertiary propargylic alcohols. Nitrogen nucleophiles such as carbamates, to-sylamides and anilines are readily alkylated at room temperature.
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