Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 353, Issue 11-12, Pages 2060-2066Publisher
WILEY-BLACKWELL
DOI: 10.1002/adsc.201100149
Keywords
aqueous chemistry; heterogeneous catalysis; room temperature reactions; SBA-15; sulfide oxidation; supported iron oxide nanoparticles
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Funding
- Payame Noor University
- Iran National Science Foundation (INSF)
- Ministerio de Ciencia e Innovacion, Gobierno de Espana [RYC-2009-04199]
- Consejeria de Ciencia e Innovacion, Junta de Andalucia [P10-FQM-6711]
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The present manuscript describes a simple, efficient and environmentally friendly room temperature aqueous catalytic approach to the selective preparation of sulfoxides from sulfides utilising low-loaded supported iron oxide nanoparticles and aqueous hydrogen peroxide as oxidant. Materials could be easily recovered from the reaction mixture and reused ten times without any loss in activity and no metal leaching was observed during the reaction. This is thus the first selective aqueous oxidation of sulfides using an iron-based heterogeneous system.
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